Home
Resource
New reactions, mechanisms, and stereochemical theory in organic chemistry
PDF
PDF format is widely accepted and good for printing.
Plug-in required
PDF-1(26.91 MB)
Citation & Export
View Usage Statistics
Staff View

Citation & Export
Hide

Simple citation

Kolakowski, Robert Vincent. New reactions, mechanisms, and stereochemical theory in organic chemistry. Retrieved from https://doi.org/doi:10.7282/T3V40TZQ

Export

Click here for information about Citation Management Tools at Rutgers.

Statistics
Hide

Description

TitleNew reactions, mechanisms, and stereochemical theory in organic chemistry
NameKolakowski, Robert Vincent (author); Williams, Lawrence J (chair); Knapp, Spencer (internal member); Seidel, Daniel (internal member); Shaw, Scott (outside member); Rutgers University; Graduate School - New Brunswick
Date Created2010
Other Date2010-10 (degree)
SubjectChemistry and Chemical Biology, Chemistry, Organic, Stereochemistry, Allene
Extentvii, 254 p. : ill.
DescriptionHere we describe a new method for the formation of allenes utilizing a Grob-like fragmentation along with a mechanistic study. The mechanism of the azide and thio acid amidation is presented. This mechanism was found to go through a thiatriazoline, and the reaction was successfully extended to the isoelectronic coupling of dithio acids with azides to form thioamide. Finally, distortional asymmetry is presented as new model for understanding stereoselectivity in sterically unbiased systems. This model deomonstrates that small ground state perturbations can lead to significant energy differences between diastereomeric tranistion states.
NotePh.D.
NoteIncludes bibliographical references
NoteIncludes vita
Noteby Robert Vincent Kolakowski
Genretheses, ETD doctoral
Persistent URLhttps://doi.org/doi:10.7282/T3V40TZQ
Languageeng
CollectionGraduate School - New Brunswick Electronic Theses and Dissertations
Organization NameRutgers, The State University of New Jersey
RightsThe author owns the copyright to this work.
Version 8.5.5
Rutgers University Libraries - Copyright ©2024